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Interfacing Oxides

(IFOX)

     
 
Publications::

Coey J.M.D.;Ariando;Pickett W.E.
Magnetism at the edge: New phenomena at oxide interfaces
MRS Bulletin 38 (2013), 1040

Oxide thin fi lms and interfaces exhibit a variety of novel magnetic phenomena, which are unknown in well-crystallized bulk material. The origin of these phenomena must be sought in the changes in electronic structure due to broken symmetry, strain, and electronic or atomic reconstruction, including oxygen and cation defects. These effects are fi rst discussed in magnetically ordered 3 d oxide thin fi lms and heterostructures, wherein a metal-insulator transition up on changing fi lm thickness may infl uence the magnetism. In heterojunctions, the interface magnetic order can be modifi ed, and exchange bias may appear. A high-temperature ferromagnetic-like response in dilute and undoped oxide fi lms appears to be associated with defects near the substrate interface. A two-dimensional electron gas emerges at interfaces of a polar oxide and SrTiO 3 , where electronic reconstruction brings electrons into the bottom of the Ti d band; ferromagnetism then emerges as a result of localized or delocalized d states in the presence of atomic defects.

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